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Issue 11, 1974
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Very strong hydrogen bonds formed between carboxylic acids and anions: trifluoroacetic and acetic acids with acetates and fluoride

Abstract

Studies on very strong H bonds have been extended to the strongest carboxylic acid CF3CO2H and its anion. The H bonds CF3CO2⋯ H–OAc (AC = MeCO), F ⋯ H–O2CCF3, and CF3CO2⋯ H–O2CCF3 have been studied in detail by both p.m.r. and i.r. spectroscopy and δ(OH)H, Kc, Δν(O–H), ΔH0, ΔG0, and ΔS0 values obtained.

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Article type: Paper
DOI: 10.1039/DT9740001125
Citation: J. Chem. Soc., Dalton Trans., 1974,0, 1125-1129
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    Very strong hydrogen bonds formed between carboxylic acids and anions: trifluoroacetic and acetic acids with acetates and fluoride

    J. H. Clark and J. Emsley, J. Chem. Soc., Dalton Trans., 1974, 0, 1125
    DOI: 10.1039/DT9740001125

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