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Issue 13, 1974
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Bonding mode of thiocyanate in palladium(II) phosphite complexes: X-ray structure of trans-dithiocyanatobis(triphenyl phosphite)palladium(II)

Stephen Jacobson,  Yau S. Wong,  Peter C. Chieh  and  Arthur J. Carty 

Abstract

In contrast to the presence of N-bonded thiocyanate groups in trans-Pd(NCS)2(PPh3)2 the phosphite compound trans-Pd(SCN)2[P(OPh)3]2 contain S-bonded thiocyanates as shown by X-ray crystallographic structure determination: antisymbiosis in the phosphine complexes appears primarily to result from steric inhibition of S-bonding rather than electronic effects.

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Article type: Paper
DOI: 10.1039/C39740000520
Citation: J. Chem. Soc., Chem. Commun., 1974,0, 520-521
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    Bonding mode of thiocyanate in palladium(II) phosphite complexes: X-ray structure of trans-dithiocyanatobis(triphenyl phosphite)palladium(II)

    S. Jacobson, Y. S. Wong, P. C. Chieh and A. J. Carty, J. Chem. Soc., Chem. Commun., 1974, 0, 520
    DOI: 10.1039/C39740000520

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