The base catalysed rearrangement of catechol mono-allyl ethers

W. David Ollis; Ratnasamy Somanathan; Ian O. Sutherland

doi:10.1039/C39740000494

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Journal of the Chemical Society, Chemical Communications

Issue 13, 1974

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The base catalysed rearrangement of catechol mono-allyl ethers

W. David Ollis , Ratnasamy Somanathan and Ian O. Sutherland

J. Chem. Soc., Chem. Commun., 1974, 494-496

DOI: 10.1039/C39740000494

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Abstract
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The base catalysed rearrangement of catechol mono-allyl ethers (1) and (4) at 78° involves successive sigmatropic rearrangements to give products that differ from those obtained by sigmatropic rearrangements under normal Claisen conditions.

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Journal of the Chemical Society, Chemical Communications

The base catalysed rearrangement of catechol mono-allyl ethers

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