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Issue 0, 1973
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Organocobalt complexes. Part I. Arene complexes derived from dodecacarbonyltetracobalt

Ihsan U. Khand,  Graham R. Knox,  Peter L. Pauson  and  William E. Watts 

Abstract

A series of tetranuclear arenecobalt carbonyls, ArHCo4(CO)9, are formed by treating hexacarbonylacetylenedicobalt complexes, (R1C2R2)Co2(CO)6, with arenes in the presence of norbornene derivatives, or from the cobalt carbonyls Co4(CO)12 and Co2(CO)8 by direct reaction with arenes. Stable complexes are obtained from alkyl- and alkoxy-benzenes, but not from halogeno- or acyl derivatives. The spectroscopic properties of the new complexes are reported.

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Article type: Paper
DOI: 10.1039/P19730000975
Citation: J. Chem. Soc., Perkin Trans. 1, 1973,0, 975-977
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    Organocobalt complexes. Part I. Arene complexes derived from dodecacarbonyltetracobalt

    I. U. Khand, G. R. Knox, P. L. Pauson and W. E. Watts, J. Chem. Soc., Perkin Trans. 1, 1973, 0, 975
    DOI: 10.1039/P19730000975

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