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Issue 6, 1973
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Structural parameters and unit cell dimensions for the tetragonal actinide tetrachlorides(Th, Pa, U, and Np) and tetrabromides (Th and Pa)

Abstract

Comparison of crystal structure parameters obtained for ThCl4 from quantitative X-ray powder data with those available from single-crystal studies has shown that it is possible to obtain reliable parameters from powder studies on simple compounds. Structure refinement based on powder data for ThCl4(R= 8·9%), PaCl4(R= 7·6%), UCl4(R= 9·5%), NpCl4(R= 9·1%), and ThBr4, (R= 11·3%) has yielded crystal structure parameters, and bond lengths for these isostructural compounds. Accurate unit cell dimensions are also reported.

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Article type: Paper
DOI: 10.1039/DT9730000686
Citation: J. Chem. Soc., Dalton Trans., 1973, 686-691
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    Structural parameters and unit cell dimensions for the tetragonal actinide tetrachlorides(Th, Pa, U, and Np) and tetrabromides (Th and Pa)

    D. Brown, T. L. Hall and P. T. Moseley, J. Chem. Soc., Dalton Trans., 1973, 686
    DOI: 10.1039/DT9730000686

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