A transient intermediate (λmax 340 nm), detected during the fast polymerization of styrene by HClO4 in CH2Cl2 at –80°, is tentatively interpreted as the polystyryl carbenium ion, and apparent rate constants derived.
M. De Sorgo, D. C. Pepper and M. Szwarc, J. Chem. Soc., Chem. Commun., 1973, 419 DOI: 10.1039/C39730000419
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