Jump to main content
Jump to site search

Issue 0, 1972
Previous Article Next Article

Intermolecular interactions in methane, carbon tetrafluoride and sulphur hexafluoride

Abstract

Spherically averaged potential energies of interaction between pairs of methane, carbon tetrafluoride and sulphur hexafluoride molecules have been determined as closely as possible using experimental gaseous viscosity data. Experimental second virial coefficients have then been used to estimate values of the first non zero multipole moment of these molecules. Third virial coefficients calculated with allowance for the triple dipole dispersion interaction agree well with experiment as do calculated self diffusion coefficients for methane.

Back to tab navigation

Article type: Paper
DOI: 10.1039/F29726801359
Citation: J. Chem. Soc., Faraday Trans. 2, 1972,68, 1359-1366
  •   Request permissions

    Intermolecular interactions in methane, carbon tetrafluoride and sulphur hexafluoride

    I. K. Snook and T. H. Spurling, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 1359
    DOI: 10.1039/F29726801359

Search articles by author

Spotlight

Advertisements