Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

Mark Wrighton; Dale Bredesen; George S. Hammond; Harry B. Gray

doi:10.1039/C39720001018

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Journal of the Chemical Society, Chemical Communications

Issue 18, 1972

Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

Mark Wrighton, Dale Bredesen, George S. Hammond and Harry B. Gray

J. Chem. Soc., Chem. Commun., 1972, 1018-1019

DOI: 10.1039/C39720001018

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Abstract
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The rate of electronic energy transfer from biacetyl triplets to Co(CN)₅(X)^n–(X = CN^–, MeCN, pyridine, N₃^–, H₂O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)₅(X)^n–, and (for X = CN^–, N₃^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.

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Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

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