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Issue 18, 1972
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Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

Abstract

The rate of electronic energy transfer from biacetyl triplets to Co(CN)5(X)n(X = CN, MeCN, pyridine, N3, H2O, or SCN) is strongly dependent on the energy of the first spin-allowed dd transition of Co(CN)5(X)n, and (for X = CN, N3, and SCN) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.

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Article type: Paper
DOI: 10.1039/C39720001018
Citation: J. Chem. Soc., Chem. Commun., 1972, 1018-1019
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    Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

    M. Wrighton, D. Bredesen, G. S. Hammond and H. B. Gray, J. Chem. Soc., Chem. Commun., 1972, 1018
    DOI: 10.1039/C39720001018

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