Degrees of association of n-pentyl lithium and n-octyl lithium in benzene

D. Margerison; J. D. Pont

doi:10.1039/TF9716700353

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Transactions of the Faraday Society

Issue 0, 1971

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Degrees of association of n-pentyl lithium and n-octyl lithium in benzene

D. Margerison and J. D. Pont

Trans. Faraday Soc., 1971, 67, 353-359

DOI: 10.1039/TF9716700353

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The degrees of association of n-pentyl lithium and n-octyl lithium in benzene at 30°C have been measured using the method of vapour pressure lowering. The value from n-pentyl lithium is 6.00 ± 0.09 [degrees of freedom (D.F.)]= 13]; the value for n-octyl lithium is 5.953 ± 0.016 (D.F. = 9). It is argued that the two compounds exist predominantly as hexamers in solution.

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Transactions of the Faraday Society

Degrees of association of n-pentyl lithium and n-octyl lithium in benzene

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