Study of fast reactions in solution using a dielectric-heating relaxation technique

K. J. Ivin; J. J. McGarvey; E. L. Simmons

doi:10.1039/TF9716700097

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Transactions of the Faraday Society

Issue 0, 1971

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Study of fast reactions in solution using a dielectric-heating relaxation technique

K. J. Ivin , J. J. McGarvey and E. L. Simmons

Trans. Faraday Soc., 1971, 67, 97-103

DOI: 10.1039/TF9716700097

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Abstract
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A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.

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Transactions of the Faraday Society

Study of fast reactions in solution using a dielectric-heating relaxation technique

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