Solid-liquid phase equilibrium in the sodium-caesium alloy system

J. Bevan Ott; J. Rex Goates; Dee E. Oyler

doi:10.1039/TF9716700031

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Transactions of the Faraday Society

Issue 0, 1971

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Solid-liquid phase equilibrium in the sodium-caesium alloy system

J. Bevan Ott , J. Rex Goates and Dee E. Oyler

Trans. Faraday Soc., 1971, 67, 31-34

DOI: 10.1039/TF9716700031

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Abstract
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Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for the sodium-caesium system. The results differ greatly from those of earlier workers, especially near the eutectic composition, where differences in melting points as large as 35 K occur. Identification of the phases involved in the peritectic halt was not conclusive, but does support the proposal that the peritectic results from the formation of an Na₂Cs intermetallic compound by a sluggish reaction.

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Transactions of the Faraday Society

Solid-liquid phase equilibrium in the sodium-caesium alloy system

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