Di-n-propyl-, di-isobutyl-, dineopentyl-, and bis(trimethylsilylmethyl)-beryllium have been prepared by an exchange reaction between diethylberyllium and the appropriate organoboranes. Dineopentylberyllium is partly associated in benzene, whereas bis(trimethylsilylmethyl)beryllium is dimeric. The reaction between diethylberyllium and tri-s-butylborane yields an insoluble crystalline hydride Et3Be2H.
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Journal of the Chemical Society A: Inorganic, Physical, Theoretical
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