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Issue 0, 1971
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Preparation of base-free beryllium alkyls from trialkylboranes. Dineopentylberyllium, bis(trimethylsilylmethyl)beryllium, and an ethylberyllium hydride

Abstract

Di-n-propyl-, di-isobutyl-, dineopentyl-, and bis(trimethylsilylmethyl)-beryllium have been prepared by an exchange reaction between diethylberyllium and the appropriate organoboranes. Dineopentylberyllium is partly associated in benzene, whereas bis(trimethylsilylmethyl)beryllium is dimeric. The reaction between diethylberyllium and tri-s-butylborane yields an insoluble crystalline hydride Et3Be2H.

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Article type: Paper
DOI: 10.1039/J19710001308
Citation: J. Chem. Soc. A, 1971,0, 1308-1310
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    Preparation of base-free beryllium alkyls from trialkylboranes. Dineopentylberyllium, bis(trimethylsilylmethyl)beryllium, and an ethylberyllium hydride

    G. E. Coates and B. R. Francis, J. Chem. Soc. A, 1971, 0, 1308
    DOI: 10.1039/J19710001308

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