Some hydroxycyclo-octenyl complexes of palladium(II)

D. A. White

doi:10.1039/J19710000145

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Issue 0, 1971

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Some hydroxycyclo-octenyl complexes of palladium(II)

D. A. White

J. Chem. Soc. A, 1971, 145-147

DOI: 10.1039/J19710000145

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Treatment of potassium tetrachloropalladite with cyclo-octa-1,5-diene in aqueous sodium carbonate in the presence of bromide ion gives di-µ-bromo-bis-(2-hydroxycyclo-oct-5-enyl)dipalladium. The preformed diene complex, 2,2,6,6-tetramethylheptane-3,5-dionato(cyclo-octa-1,5-diene)palladium tetrafluoroborate gives a hydroxycyclo-octenyl complex with aqueous sodium carbonate. A convenient preparation of the above cationic diene complex (and some similar complexes) is reported.

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Some hydroxycyclo-octenyl complexes of palladium(II)

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