A Raman spectroscopic study of dimanganese and dirhenium decacarbonyls

D. M. Adams; M. A. Hooper; A. Squire

doi:10.1039/J19710000071

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Issue 0, 1971

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A Raman spectroscopic study of dimanganese and dirhenium decacarbonyls

D. M. Adams , M. A. Hooper and A. Squire

J. Chem. Soc. A, 1971, 71-77

DOI: 10.1039/J19710000071

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Abstract
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New Raman data for solutions, powders, and oriented single crystals are reported which allow a consistent assignment of the vibrational spectra of the title compounds. The four Raman-active ν(CO) modes for Mn₂(CO)₁₀ are at 2116(a₁), 2024(e₂), 1997(a₁), and 1981(e₃) cm^–1. Low-frequency spectra of considerably improved quality are also presented. All of the a₁ bands have been located for Re₂(CO)₁₀ and all but one for Mn₂(CO)₁₀ for solutions.

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

A Raman spectroscopic study of dimanganese and dirhenium decacarbonyls

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