Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

J. Burgess; G. E. Ellis; D. J. Evans; A. Porter; R. Wane; R. D. Wyvill

doi:10.1039/J19710000044

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Issue 0, 1971

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Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

J. Burgess , G. E. Ellis , D. J. Evans , A. Porter , R. Wane and R. D. Wyvill

J. Chem. Soc. A, 1971, 44-48

DOI: 10.1039/J19710000044

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Kinetics of reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in a range of aqueous alcohols indicate a bimolecular reaction mechanism. Second-order rate constants correlate with rate constants for aquation of the respective complexes, and with Grunwald–Winstein solvent Y values.

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J. Burgess
G. E. Ellis
D. J. Evans
A. Porter
R. Wane
R. D. Wyvill

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

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