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Issue 0, 1971
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Some new π-cyclopentadienylruthenium complexes

T. Blackmore,  M. I. Bruce  and  F. G. A. Stone 

Abstract

Synthesis of the complexes (π-C5H5)Ru(L)2Cl [L = PPh3, PPh2Me, P(OMe)3, AsPh3] and the related osmium compound (π-C5H5)Os(PPh3)2Br are described. Reactions of (π-C5H5)Ru(PPh3)2Cl of three types were investigated: (a) replacement of the Cl atom by, e.g. H, Me, C6F5, or SnCl3 groups; (b) replacement of one of the phosphine ligands by, e.g. CO, PPh2Me; (c) formation of cationic complexes of the type [(π-C5H5)Ru(PPh3)2L]+, e.g. L = CO, MeCN. Two unusual complexes, (π-C5H5)Ru(PPh3)2BH4, and the hexachlorodizincate, [(π-C5H5)-Ru(PPh3)2(MeCN)]2Zn2Cl6, are also reported.

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Article type: Paper
DOI: 10.1039/J19710002376
Citation: J. Chem. Soc. A, 1971,0, 2376-2382
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    Some new π-cyclopentadienylruthenium complexes

    T. Blackmore, M. I. Bruce and F. G. A. Stone, J. Chem. Soc. A, 1971, 0, 2376
    DOI: 10.1039/J19710002376

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