1,3- and 1,6-Addition of electronegatively substituted olefins to co-ordinated cycloheptatriene and N-methoxycarbonylazepine: X-ray diffraction study of the tricarbonylcycloheptatrieneiron–tetracyanoethylene adduct

M. Green; Susan Tolson; J. Weaver; D. C. Wood; P. Woodward

doi:10.1039/C2971000222B

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1,3- and 1,6-Addition of electronegatively substituted olefins to co-ordinated cycloheptatriene and N-methoxycarbonylazepine: X-ray diffraction study of the tricarbonylcycloheptatrieneiron–tetracyanoethylene adduct

M. Green, Susan Tolson, J. Weaver, D. C. Wood and P. Woodward

Abstract

A single-crystal X-ray diffraction study establishes that tetracyanoethylene undergoes a 1,3-addition reaction to tricarbonylcycloheptatrieneiron, with formation of a novel 2,3,4,6-tetrahapto-bonded system: the corresponding reaction with tricarbonyl-N-methoxy-carbonylazepine-ruthenium or -iron affords, respectively, a 1,3 adduct or a mixture of 1,6 and 1,3 adducts.

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Article type: Paper

DOI: 10.1039/C2971000222B

Citation: J. Chem. Soc. D, 1971,0, 222b-223

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1,3- and 1,6-Addition of electronegatively substituted olefins to co-ordinated cycloheptatriene and N-methoxycarbonylazepine: X-ray diffraction study of the tricarbonylcycloheptatrieneiron–tetracyanoethylene adduct

M. Green, S. Tolson, J. Weaver, D. C. Wood and P. Woodward, J. Chem. Soc. D, 1971, 0, 222b
DOI: 10.1039/C2971000222B
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Journal of the Chemical Society D: Chemical Communications

1,3- and 1,6-Addition of electronegatively substituted olefins to co-ordinated cycloheptatriene and N-methoxycarbonylazepine: X-ray diffraction study of the tricarbonylcycloheptatrieneiron–tetracyanoethylene adduct

Abstract

1,3- and 1,6-Addition of electronegatively substituted olefins to co-ordinated cycloheptatriene and N-methoxycarbonylazepine: X-ray diffraction study of the tricarbonylcycloheptatrieneiron–tetracyanoethylene adduct

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