Issue 8, 1971

An electron-rich olefin as a source of co-ordinated carbene; synthesis of trans-PtCl2[C(NPhCH2)2]PEt3

Abstract

Interaction of the appropriate electron-rich olefin and chloride bridged PtII dimer has yielded the unreactive trans-PtII carbene complex (I) which is belived to isomerise thermally to the cis-isomer; the structure of the trans-complex is established inter alia by a single crystal X-ray analysis.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 400-401

An electron-rich olefin as a source of co-ordinated carbene; synthesis of trans-PtCl2[C(NPhCH2)2]PEt3

D. J. Cardin, B. Cetinkaya, M. F. Lappert, Lj. Manojlović-Muir and K. W. Muir, J. Chem. Soc. D, 1971, 400 DOI: 10.1039/C29710000400

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