In cis- and trans-dichloro[CH:CH·(CH2)n·[graphic omitted]H(Me)Et](benzylamine)platinum(II) complexes, the asymmetric carbon atom originally present in the olefin induces the opposite absolute configuration in the tertiary carbon atom bound to Pt and, at least in the cis-complexes, the extent of asymmetric induction rapidly diminishes with increasing n.
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