The lanthanide cations are shown to excellent n.m.r. probes of their immediate co-ordinated neighbours and of their environment in enzymes including more distant molecules such as bound substrates.
K. G. Morallee, E. Nieboer, F. J. C. Rossotti, R. J. P. Williams, A. V. Xavier and R. A. Dwek, J. Chem. Soc. D, 1970, 1132 DOI: 10.1039/C29700001132
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