Rearrangement under electron impact seems to be a general property of phenylboronates of diols: depending on the structure of the ester the products of rearrangement are hydrocarbon ions containing 7, 8, 9, and/or 10 carbon atoms.
I. R. McKinley and H. Weigel, J. Chem. Soc. D, 1970, 1022 DOI: 10.1039/C29700001022
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