All the geometric and optical isomers possible for the [Co(dien)2]3+ system have been isolated and characterised, and the geometric configurations have been assigned from the difference in racemisation behaviour of the optical forms of the u-cis- and trans-isomers and from the 1H n.m.r. spectra.
F. R. Keene, G. H. Searle, Y. Yoshikawa, A. Imai and K. Yamasaki, J. Chem. Soc. D, 1970, 784 DOI: 10.1039/C29700000784
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