Jump to main content
Jump to site search

Issue 7, 1970
Previous Article Next Article

Pentachalcogenide dianions in transition-metal complexes: crystal structure of bis-(π-cyclopentadienyl)titanium pentasulphide

Abstract

The anionic pentasulphide chain S52– acts as a bidentate ligand to form the “hetero-cyclohexahalcogen”(C5H5)2TiS5: the TiS5 ring fragment has the chair conformation with Ti–S bond lengths of 2·420 and 2·446 Å and S–S bond lengths which range from 2·051–2·059 Å.

Back to tab navigation
Please wait while Download options loads

Article type: Paper
DOI: 10.1039/C29700000410
Citation: J. Chem. Soc. D, 1970, 410-411
  •   Request permissions

    Pentachalcogenide dianions in transition-metal complexes: crystal structure of bis-(π-cyclopentadienyl)titanium pentasulphide

    E. F. Epstein and I. Bernal, J. Chem. Soc. D, 1970, 410
    DOI: 10.1039/C29700000410

Search articles by author