Jump to main content
Jump to site search
Publishing
Advanced

Volume 65, 1969
Previous Article Next Article

Kinetics of the reaction of metal alkyl compounds with alkenes. Part 4.—The dissociation of aluminium triethyl dimer

J. N. Hay,  P. G. Hooper  and  J. C. Robb 

Abstract

The vapour pressure of aluminium triethyl is measured in the range 60–120°C, and found to obey the relationship log10p= 10.85–3613/T, which gives values of 186°C, 16.5 kcal/mole of vapour and 35.9 cal/mole deg. for the boiling point, heat of vaporization and Trouton's constant. These values are anomalous and are attributed to the presence of association, 2AlEt3⇌Al2Et6. The heat of association is –10.2 kcal/mole of Al2Et6. This value is used to evaluate the Arrhenius parameters of the reaction of aluminium triethyl monomer and α-alkenes.

Back to tab navigation
Download options Please wait...

Article type: Paper
DOI: 10.1039/TF9696501365
Citation: Trans. Faraday Soc., 1969,65, 1365-1371
  •   Request permissions

    Kinetics of the reaction of metal alkyl compounds with alkenes. Part 4.—The dissociation of aluminium triethyl dimer

    J. N. Hay, P. G. Hooper and J. C. Robb, Trans. Faraday Soc., 1969, 65, 1365
    DOI: 10.1039/TF9696501365

    If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.

    Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.
    • For reproduction of material from PCCP:
      Reproduced from Ref. XX with permission from the PCCP Owner Societies.
    • For reproduction of material from PPS:
      Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.
    • For reproduction of material from all other RSC journals and books:
      Reproduced from Ref. XX with permission from The Royal Society of Chemistry.

    If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

    In all cases the Ref. XX is the XXth reference in the list of references.

    If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC
    • For reproduction of material from PCCP:
      [Original citation] - Reproduced by permission of the PCCP Owner Societies
    • For reproduction of material from PPS:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC
    • For reproduction of material from all other RSC journals:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry

    If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements