Jump to main content
Jump to site search

Issue 2, 1969
Previous Article Next Article

An abnormal Claisen rearrangement of 3,3-dimethylallyl oestrone ether

Abstract

Rearrangement of 3,3-dimethylallyl oestrone ether gives mainly 2-(1,2-dimethylallyl) oestrone. The normal Claisen product, 2-(1,1-dimethylallyl)oestrone was not isolated until it was first trapped as its butyric ester.2-(1,1-Dimethylallyl)oestrone was transformed into the 2-(1,2-dimethylallyl) isomer under the conditions of the Claisen rearrangement.

Back to tab navigation

Article type: Paper
DOI: 10.1039/J39690000243
Citation: J. Chem. Soc. C, 1969,0, 243-245
  •   Request permissions

    An abnormal Claisen rearrangement of 3,3-dimethylallyl oestrone ether

    A. Jefferson and F. Scheinmann, J. Chem. Soc. C, 1969, 0, 243
    DOI: 10.1039/J39690000243

Search articles by author

Spotlight

Advertisements