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Issue 13, 1969
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Preparation of some N-aminotriazolo-pyridines and -quinolines, their oxidation with lead tetra-acetate, and the trapping of the resulting pyridynes and quinolynes with tetraphenylcyclopentadienone (tetracyclone)

Abstract

The preparations of 1-aminotriazolo[4,5-c]pyridine (4), 3-aminotriazolo[4,5-b]pyridine (9), 1-aminotriazolo-[4,5-c]quinoline (14), and 3-aminotriazolo-[4,5-b]quinoline (18) are described. The oxidation of these compounds with lead tetra-acetate in the presence of tetraphenylcyclopentadienone gave the products expected from the trapping of 3,4-pyridyne, 2,3-pyridyne, 3,4-quinolyne, and 2,3-quinolyne respectively. The adducts of 2,3-pyridyne and 2,3-quinolyne were obtained only in low yield.

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Article type: Paper
DOI: 10.1039/J39690001758
Citation: J. Chem. Soc. C, 1969, 1758-1763
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    Preparation of some N-aminotriazolo-pyridines and -quinolines, their oxidation with lead tetra-acetate, and the trapping of the resulting pyridynes and quinolynes with tetraphenylcyclopentadienone (tetracyclone)

    G. W. J. Fleet and I. Fleming, J. Chem. Soc. C, 1969, 1758
    DOI: 10.1039/J39690001758

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