Electrophilic attack of the trityl cation on an aminobenzenethiol gives the corresponding sulphide. The presence of the amino-substituent, a powerful activator of the benzene ring, does not prevent sulphide formation at the thiol group. Valence-shell expansion of sulphur appears to explain these results.
G. Chuchani and K. S. Heckmann, J. Chem. Soc. C, 1969, 1436 DOI: 10.1039/J39690001436
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...