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Issue 0, 1969
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Structure and infrared spectra of some nitrato-complexes of cobalt(II), nickel(II), copper(II), and zinc(II) with heterocyclic ligands

E. J. Duff,  M. N. Hughes  and  K. J. Rutt 

Abstract

The structures of fifteen nitrato-complexes ML2(NO3)2[M = Co, Ni, Cu, or Zn; L = benzothiazole, 2-methylbenzothiazole, benzoxazole, or 2-methylbenzoxazole (2-Me-bo)] are discussed with emphasis on their i.r. spectra. With the exception of Ni(2-Me-bo)2(NO3)2 which appears to be polymeric with bridging nitrate, all complexes have bidenate nitrato-groups. Two ‘metal–oxygen’ stretching frequencies are observed for most complexes, and the band separation is related to the nature of the metal–oxygen bond.

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Article type: Paper
DOI: 10.1039/J19690002126
Citation: J. Chem. Soc. A, 1969,0, 2126-2128
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    Structure and infrared spectra of some nitrato-complexes of cobalt(II), nickel(II), copper(II), and zinc(II) with heterocyclic ligands

    E. J. Duff, M. N. Hughes and K. J. Rutt, J. Chem. Soc. A, 1969, 0, 2126
    DOI: 10.1039/J19690002126

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