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Issue 0, 1969
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Phosphorus–fluorine chemistry. Part XX. Redox disproportionation of difluorophosphines, RPF2, with electronegative substituents R

Abstract

Difluorophosphines, RPF2, containing the electronegative substituents, R = CF3 and C6H5, will undergo redox disproportionation with formation of tetrafluorophosphoranes and cyclopolyphosphines, in accord with the overall equation 10 RPF2 5 RPF4+(RP)n(n= 4, 5 for R = CF3; n= 5 for R = C6H5). The identity of the products, all previously known, was established by comparison of their physical properties (n.m.r. and mass spectra, i.r. spectra, X-ray powder diagram, etc.) to those of the authentic compounds.

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Article type: Paper
DOI: 10.1039/J19690000702
Citation: J. Chem. Soc. A, 1969, 702-703
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    Phosphorus–fluorine chemistry. Part XX. Redox disproportionation of difluorophosphines, RPF2, with electronegative substituents R

    H. G. Ang and R. Schmutzler, J. Chem. Soc. A, 1969, 702
    DOI: 10.1039/J19690000702

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