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Issue 0, 1968
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Photochemical behaviour of bridged compounds. Part II. Photolytic and some ground state reactions of carbonyl-bridged anhydrides and their decarbonylation products

Abstract

7-Oxonorborn-2-ene-5,6-dicarboxylic anhydrides (I) and cyclohexa-1,3-diene-5,6-dicarboxylic anhydrides (II), with various substituting or fused groups, give substituted benzenes (III) in substitution-dependent yields when irradiated at 2537 Å. A possible rationale for the photolytic decarbonylation is discussed. Some synthetic and ground state reactions of the systems studied are also described.

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Article type: Paper
DOI: 10.1039/J39680000068
Citation: J. Chem. Soc. C, 1968,0, 68-71
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    Photochemical behaviour of bridged compounds. Part II. Photolytic and some ground state reactions of carbonyl-bridged anhydrides and their decarbonylation products

    B. Fuchs, J. Chem. Soc. C, 1968, 0, 68
    DOI: 10.1039/J39680000068

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