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Issue 0, 1968
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Nitrogen-14 chemical shifts in ureas

Abstract

14 N chemical shifts have been measured in some ureas and thioureas using double-irradiation techniques whilst observing the 1H n.m.r. spectra of the compounds. The values are compared with those obtained previously for amides, and the results indicate that the 14N chemical shift variations found in ureas and amides are governed by the degree of delocalisation of the nitrogen lone pair of electrons. The 14N chemical shift of selenourea is also recorded.

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Article type: Paper
DOI: 10.1039/J29680000673
Citation: J. Chem. Soc. B, 1968,0, 673-675
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    Nitrogen-14 chemical shifts in ureas

    P. Hampson and A. Mathias, J. Chem. Soc. B, 1968, 0, 673
    DOI: 10.1039/J29680000673

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