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Protonation equilibria of amides and related compounds. Part II. Butyramide, N-butyrylglycine, and some carbamic acid esters

V. C. Armstrong  and  R. B. Moodie 

Abstract

Studies of the n.m.r. spectra of solutions of butyramide, N-butyrylglycine, methyl carbamate, ethyl carbamate, ethyl N-methylcarbamate, ethyl NN-dimethylcarbamate, and N-ethoxycarbonylglycine in aqueous sulphuric and aqueous perchloric acids reveal that the protonation behaviour of carbamic acid esters is similar to that of amides, and they are intermediate in basicity between structurally similar amides and esters.

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Article type: Paper
DOI: 10.1039/J29680000275
Citation: J. Chem. Soc. B, 1968,0, 275-277
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    Protonation equilibria of amides and related compounds. Part II. Butyramide, N-butyrylglycine, and some carbamic acid esters

    V. C. Armstrong and R. B. Moodie, J. Chem. Soc. B, 1968, 0, 275
    DOI: 10.1039/J29680000275

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