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Issue 0, 1968
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Electron impact-induced rearrangements in compounds having the P[double bond, length half m-dash]S bond

Abstract

The fragmentation processes of P[double bond, length half m-dash]S compounds upon electron impact include the following bond-forming reactions: (i) molecular ion rerrangement of the type –P(:S)O–R –P(:O)S–R, (ii) bond formation between substituents (especially aryl groups) on phosphorus, (iii) loss of SH· from the molecular ion where the hydrogen can be derived from an alkyl or an aryl group, and (iv) hydrogen rearrangement to give the phenol molecular ion (or an isomer) in compounds having a phenoxy-substituent.

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Article type: Paper
DOI: 10.1039/J29680001327
Citation: J. Chem. Soc. B, 1968,0, 1327-1333
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    Electron impact-induced rearrangements in compounds having the P[double bond, length half m-dash]S bond

    R. G. Cooks and A. F. Gerrard, J. Chem. Soc. B, 1968, 0, 1327
    DOI: 10.1039/J29680001327

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