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Vibrational and electronic spectra of transition-metal carbonyl complexes. Part III. The infrared spectra of some carbonyl complexes containing metal–metal bonds

Linda M. Bower  and  M. H. B. Stiddard 

Abstract

Precise measurements of the i.r. spectra of a number of carbonyl complexes have been made. The complexes, which contain metal–metal bonds, are of two types: (i) LMn(CO)5, LRe(CO)5, and LCo(CO)4, (where L = a metal system, e.g., Ph3Sn or Ph3PAu, and (ii) monosubstituted tertiary-phosphine derivatives of these complexes. The assignment of bands in the fundamental C–O stretching region has been based upon intensity and energy considerations together with binary combination data.

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Article type: Paper
DOI: 10.1039/J19680000706
Citation: J. Chem. Soc. A, 1968,0, 706-710
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    Vibrational and electronic spectra of transition-metal carbonyl complexes. Part III. The infrared spectra of some carbonyl complexes containing metal–metal bonds

    L. M. Bower and M. H. B. Stiddard, J. Chem. Soc. A, 1968, 0, 706
    DOI: 10.1039/J19680000706

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