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Issue 0, 1967
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Heats of reaction of silicon, germanium, and tin tetrahalides with pyridine and isoquinoline

J. M. Miller  and  M. Onyszchuk 

Abstract

Heats of formation of crystalline MX4,2L complexes (where M = Si, Ge, or Sn; L = pyridine or isoquinoline; X = F, Cl, or Br, except X = Cl only when M = Sn) have been measured calorimetrically. Values decrease in the order MF4 > MCl4 > MBr4, GeX4 > SiX4, and SnCl4 > GeCl4 > SiCl4, except that those for SiCl4,2py and SiBr4,2py are abnormally high. Comparisons are drawn with results from other sources and attempts are made to explain the observed orders.

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Article type: Paper
DOI: 10.1039/J19670001132
Citation: J. Chem. Soc. A, 1967,0, 1132-1135
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    Heats of reaction of silicon, germanium, and tin tetrahalides with pyridine and isoquinoline

    J. M. Miller and M. Onyszchuk, J. Chem. Soc. A, 1967, 0, 1132
    DOI: 10.1039/J19670001132

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