Jump to main content
Jump to site search

Issue 0, 1967
Previous Article Next Article

Mössbauer spectra of iron(III) diketone complexes

Abstract

The Mössbauer spectra of trisacetylacetonatoiron(III) and seven of its ligand-substituted derivatives have been recorded at liquid-nitrogen temperature. In many cases asymmetric peaks were obtained. All chemical shifts were close to 0·62 mm./sec.

A computer analysis showed quadrupole splittings ranging up to 0·75 mm./sec. The asymmetry of the two lines is interpreted in terms of electronic relaxation processes in the solid. From the relative broadening of the two absorption lines the sign of the electric-field gradient at the nucleus can be deduced.

Back to tab navigation

Article type: Paper
DOI: 10.1039/J19670001966
Citation: J. Chem. Soc. A, 1967,0, 1966-1971
  •   Request permissions

    Mössbauer spectra of iron(III) diketone complexes

    G. M. Bancroft, A. G. Maddock, W. K. Ong, R. H. Prince and A. J. Stone, J. Chem. Soc. A, 1967, 0, 1966
    DOI: 10.1039/J19670001966

Search articles by author

Spotlight

Advertisements