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Thermochemistry of transition-metal complexes. Part I. CoLnX2 complexes; n= 4 or 2; L = pyridine, α-, β-, γ-picoline, quinoline, and aniline; X = Cl, Br, I

G. Beech,  C. T. Mortimer  and  E. G. Tyler 

Abstract

Quantitative differential thermal analysis has been used to determine the heats, at temperatures up to 350°, of the thermal decompositions CoLnX2(cryst.)→ CoX2(cryst.)+nL(g), where n= 4 or 2, and L and X are the atoms and molecules indicated in the title. Comment is made on the variation of the heats of reaction.

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Article type: Paper
DOI: 10.1039/J19670000925
Citation: J. Chem. Soc. A, 1967,0, 925-928
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    Thermochemistry of transition-metal complexes. Part I. CoLnX2 complexes; n= 4 or 2; L = pyridine, α-, β-, γ-picoline, quinoline, and aniline; X = Cl, Br, I

    G. Beech, C. T. Mortimer and E. G. Tyler, J. Chem. Soc. A, 1967, 0, 925
    DOI: 10.1039/J19670000925

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