Ionisation constants of some substituted quinazolines and triazanaphthalenes

J. W. Bunting; D. D. Perrin

doi:10.1039/J29660000436

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Journal of the Chemical Society B: Physical Organic

Issue 0, 1966

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Ionisation constants of some substituted quinazolines and triazanaphthalenes

J. W. Bunting and D. D. Perrin

J. Chem. Soc. B, 1966, 436-438

DOI: 10.1039/J29660000436

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Abstract
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As ordinarily measured, the pK_a values of many substituted quinazolines and triazanaphthalenes are composite because of reversible covalent hydration of the cations. By using a rapid-reaction apparatus, the true pK_a values of some of these compounds have been obtained and the equilibrium concentration ratios of hydrated to “anhydrous” cations have been calculated. The true pK_a values of pteridine is predicted from the present results.

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Journal of the Chemical Society B: Physical Organic

Ionisation constants of some substituted quinazolines and triazanaphthalenes

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