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Vibration spectra and structure of some pentafluorotellurate(IV) complexes

N. N. Greenwood,  A. C. Sarma  and  B. P. Straughan 

Abstract

Pentafluorotellurate complexes, MTeF5, where M = K, Rb, Cs, NH4, and C5H5NH, have been prepared, and their infrared and Raman spectra have been recorded. Molecular weight and conductivity measurements indicate that the pyridinium complex is a 1 : 1 electrolyte in solution, and the vibration spectra show that the discrete TeF5– ion persists in the solid phase. Detailed assignments of the infrared and Raman spectra of the crystalline complexes suggest a square-pyramidal (C4r) structure for the pentafluorotellurate(IV) ion.

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Article type: Paper
DOI: 10.1039/J19660001446
Citation: J. Chem. Soc. A, 1966,0, 1446-1447
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    Vibration spectra and structure of some pentafluorotellurate(IV) complexes

    N. N. Greenwood, A. C. Sarma and B. P. Straughan, J. Chem. Soc. A, 1966, 0, 1446
    DOI: 10.1039/J19660001446

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