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Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part IV. Enthalpies of transfer of the alkali-metal halides from water to a 20% mixture of dioxan and water

D. Feakins,  B. C. Smith  and  Lambodar Thakur 

Abstract

Enthalpies of solution have been determined for the alkali-metal chlorides and sodium and potassium bromides and iodides in 20 wt.% mixtures of dioxan in water, and enthalpies of transfer (ΔHt°) from water to this mixture calculated therefrom. The ΔHt° values are compared with those for the methanol–water system and are interpreted in terms of a structural theory of ion solvation developed in earlier Papers in this Series.

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Article type: Paper
DOI: 10.1039/J19660000714
Citation: J. Chem. Soc. A, 1966,0, 714-718
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    Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part IV. Enthalpies of transfer of the alkali-metal halides from water to a 20% mixture of dioxan and water

    D. Feakins, B. C. Smith and L. Thakur, J. Chem. Soc. A, 1966, 0, 714
    DOI: 10.1039/J19660000714

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