Issue 21, 2013
From the journal:

Dalton Transactions

Synthesis and X-ray structural characterization of the (chlorochalcogeno)phosphonium cations R2R′PSCl+ and R2R′PSeCl+ as their AuCl4− salts†‡

Daniel Upmanna  and  Peter G. Jones*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie, Technische Universität Carolo-Wilhelmina, Hagenring 30, D-38106 Braunschweig, Germany
E-mail: p.jones@tu-bs.de
Fax: +49 531-391-5387
Tel: +49 531-391-5382

Abstract

Phosphine chalcogenides R2R′PE react with (tht)AuCl to form complexes of the type R2R′PEAuCl (E = S, Se); stepwise oxidation with PhICl2 leads first to R2R′PEAuCl3 and then to the (chlorochalcogeno)phosphonium salts R2R′PECl+AuCl4−.

Graphical abstract: Synthesis and X-ray structural characterization of the (chlorochalcogeno)phosphonium cations R2R′PSCl+ and R2R′PSeCl+ as their AuCl4− salts

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Article information

DOI
https://doi.org/10.1039/C3DT50777G
Article type
Communication
Submitted
22 Mar 2013
Accepted
08 Apr 2013
First published
08 Apr 2013

Dalton Trans., 2013,42, 7526-7528

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Synthesis and X-ray structural characterization of the (chlorochalcogeno)phosphonium cations R2R′PSCl+ and R2R′PSeCl+ as their AuCl4− salts

D. Upmann and P. G. Jones, Dalton Trans., 2013, 42, 7526 DOI: 10.1039/C3DT50777G

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