Issue 6, 2016
From the journal:

Dalton Transactions

Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster†

Tomohiko Hamaguchi,a   Michael D. Doud,b   Jeremy Hilgar,b   Jeffrey D. Rinehartb  and  Clifford P. Kubiak*b  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan

b Department of Chemistry and Biochemistry, University of California – San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, CA 92093-0358, USA
E-mail: ckubiak@ucsd.edu

Abstract

A new hexagonal bipyramidal Ni8 cluster is reported and its magnetic behaviour is analyzed. The molecular structure consists of a hexagonal wheel capped by two additional apical Ni2+ ions. This structure supports ferromagnetic superexchange interactions between adjacent Ni2+ ions in the wheel and an antiferromagnetic superexchange interaction between the wheel and apical Ni2+ ions.

Graphical abstract: Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster

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Article information

DOI
https://doi.org/10.1039/C5DT04861C
Article type
Communication
Submitted
12 Dec 2015
Accepted
04 Jan 2016
First published
05 Jan 2016

Dalton Trans., 2016,45, 2374-2377

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Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster

T. Hamaguchi, M. D. Doud, J. Hilgar, J. D. Rinehart and C. P. Kubiak, Dalton Trans., 2016, 45, 2374 DOI: 10.1039/C5DT04861C

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