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Communication
Chem. Commun., 2009, 6747 - 6749, DOI: 10.1039/b910473a
Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes
Wojciech Cha
adaj and Janusz Jurczak
This study investigates, experimentally and computationally, the role played by the structure of the diamine moiety of salen chromium complexes in determining the catalyst conformational equilibrium and, in consequence, the direction of asymmetric induction in metallosalen-catalyzed reactions of aldehydes.
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