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Chem. Commun., 2009, 4266 - 4268, DOI: 10.1039/b905727g


Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

Velusamy Subbarayan, Joshua V. Ruppel, Shifa Zhu, Jason A. Perman and X. Peter Zhang


A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.

Graphical abstract image for this article  (ID: b905727g)