Issue 7, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and structural characterization of a novel C3-chiral triamine and its trilithium triamide

Patrick Renner,a   Christian H. Galka,a   Lutz H. Gade,*a   Sanja Radojevicb  and  Mary McPartlinb  

* Corresponding authors

a Laboratoire de Chimie Organométallique et de Catalyse (CNRS UMR 7513), Institut Le Bel, Université Louis Pasteur Strasbourg, 4, rue Blaise Pascal, Strasbourg Cedex, France
E-mail: Gade@chimie.u-strasbg.fr

b School of Applied Chemistry, University of North London, Holloway Road, London, UK

Abstract

The novel C3-chiral tripodal amine HC(SiMe2NHR*)3 (1) and the corresponding trilithium triamide HC(SiMe2N(Li)R*) (2) [R* = (R)-tetrahydronaphthyl] have been synthesized and characterized by X-ray diffraction; the latter was found to have a central adamantoid cage structure in which the two-coordinate Li atoms are internally solvated by the peripheral aryl groups.

Graphical abstract: Synthesis and structural characterization of a novel C3-chiral triamine and its trilithium triamide

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Article information

DOI
https://doi.org/10.1039/B100719J
Article type
Communication
Submitted
19 Jan 2001
Accepted
01 Mar 2001
First published
15 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 964-965

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Synthesis and structural characterization of a novel C3-chiral triamine and its trilithium triamide

P. Renner, C. H. Galka, L. H. Gade, S. Radojevic and M. McPartlin, J. Chem. Soc., Dalton Trans., 2001, 964 DOI: 10.1039/B100719J

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