Issue 34, 2015

Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(i) salts

Abstract

A very high-yielding Pd-catalyzed cross-coupling between aryl halides and aryl(trialkoxy)silanes is achieved in the presence of Cu(I) and a measured amount of water. This novel methodology is useful for the generation of a wide range of biaryls, particularly non-para substituted derivatives, which are usually less reported.

Graphical abstract: Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(i) salts

Supplementary files

Article information

Article type
Communication
Submitted
02 Mar 2015
Accepted
09 Mar 2015
First published
09 Mar 2015

RSC Adv., 2015,5, 26796-26800

Author version available

Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(I) salts

C. I. Traficante, E. G. Mata and C. M. L. Delpiccolo, RSC Adv., 2015, 5, 26796 DOI: 10.1039/C5RA03732H

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