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Issue 37, 2015
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Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

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Abstract

This paper provides evidence of formerly unknown thioether coordination in metal alkoxides. The thioether functionalised alkanols serving as alcoholate ligands have been prepared by a generic route. The gallium and indium alkoxides provide the first evidence for sulphur coordination in the liquid and solid state in metal alkoxide derivatives. The presence of amines suppresses the coordination of thioether moieties leading to a well-known bonding mode in aminoalcoholates.

Graphical abstract: Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

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Publication details

The article was received on 21 Jul 2015, accepted on 20 Aug 2015 and first published on 20 Aug 2015


Article type: Paper
DOI: 10.1039/C5DT02777B
Citation: Dalton Trans., 2015,44, 16439-16445
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    Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

    S. Barth, F. Biegger and M. Puchberger, Dalton Trans., 2015, 44, 16439
    DOI: 10.1039/C5DT02777B

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