Issue 13, 2014

Rationale for the sluggish oxidative addition of aryl halides to Au(i)

Abstract

The oxidative addition of Csp2–Br or Csp2–I bonds to gold(I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish.

Graphical abstract: Rationale for the sluggish oxidative addition of aryl halides to Au(i)

Supplementary files

Article information

Article type
Communication
Submitted
21 Nov 2013
Accepted
04 Dec 2013
First published
04 Dec 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 1533-1536

Author version available

Rationale for the sluggish oxidative addition of aryl halides to Au(I)

M. Livendahl, C. Goehry, F. Maseras and A. M. Echavarren, Chem. Commun., 2014, 50, 1533 DOI: 10.1039/C3CC48914K

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