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Issue 13, 2011
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Solvent-hindered intramolecular vibrational redistribution

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Abstract

Ultrafast two-dimensional infrared spectroscopy and molecular dynamics simulations of Mn2(CO)10 in a series of linear alcohols reveal that the rate of intramolecular vibrational redistribution among the terminal carbonyl stretches is dictated by the average number of hydrogen bonds formed between the solute and solvent. The presence of hydrogen bonds was found to hinder vibrational redistribution between eigenstates, while leaving the overall T1 relaxation rate unchanged.

Graphical abstract: Solvent-hindered intramolecular vibrational redistribution

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Publication details

The article was received on 12 Oct 2010, accepted on 07 Feb 2011 and first published on 28 Feb 2011


Article type: Communication
DOI: 10.1039/C0CP02138E
Citation: Phys. Chem. Chem. Phys., 2011,13, 5579-5583
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    Solvent-hindered intramolecular vibrational redistribution

    J. T. King, J. M. Anna and K. J. Kubarych, Phys. Chem. Chem. Phys., 2011, 13, 5579
    DOI: 10.1039/C0CP02138E

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