Pyridine-functionalized organic porous polymers: applications in efficient CO2 adsorption and conversion

Zhenzhen Yang; Huan Wang; Guipeng Ji; Xiaoxiao Yu; Yu Chen; Xinwei Liu; Cailing Wu; Zhimin Liu

doi:10.1039/C6NJ03899A

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Pyridine-functionalized organic porous polymers: applications in efficient CO₂ adsorption and conversion†

Zhenzhen Yang,^a Huan Wang,^ab Guipeng Ji,^ab Xiaoxiao Yu,^ab Yu Chen,^ab Xinwei Liu,^ab Cailing Wu^ab and Zhimin Liu

*^ab

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Pyridine-functionalized porous organic polymers showed excellent CO₂ uptake capacity (up to 63 and 171 mg g⁻¹ at 0.1 and 1 bar at 273 K), and performed well as supports for Ru(0) nanoparticles. The resultant CarPy-CMP@Ru served as an efficient catalyst for the formylation of amines with CO₂/H₂, together with high product yields (89–93%), high stability and easy recyclability.

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Article information

DOI: https://doi.org/10.1039/C6NJ03899A
Article type: Letter
Submitted: 14 Dec 2016
Accepted: 27 Feb 2017
First published: 28 Feb 2017

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New J. Chem., 2017,41, 2869-2872

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Pyridine-functionalized organic porous polymers: applications in efficient CO₂ adsorption and conversion

Z. Yang, H. Wang, G. Ji, X. Yu, Y. Chen, X. Liu, C. Wu and Z. Liu, New J. Chem., 2017, 41, 2869 DOI: 10.1039/C6NJ03899A

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